摘要
工业莰烯在耐高温离子交换树脂DCP催化作用下与无水乙醇反应生成了异龙脑基乙醚。探索了反应温度、反应时间、催化剂用量,以及工业莰烯与无水乙醇的配比对反应的影响。结果表明,异龙脑基乙醚合成的优化条件为：m（工业莰烯）∶m（无水乙醇）=10∶7-10∶9,DCP用量占物料总质量的15%,反应温度（75±1）℃,反应时间6-9 h,工业莰烯转化率达到71.5%,选择性达到96.8%。
Isobornyl ethyl ether was prepared by ethoxylation of camphene with absolute ethanol in the presence of DCP heatresistant ion exchange resin. The optimum reaction conditions are as follows： mass ratio of camphene to absolute ethanol is 10：7 - 10：9, the mass ratio of catalyst to total is 15 % , reaction temperature is （75 ± 1 ）℃ and reaction time is 6-9 h. Under the optimum conditions the conversion of camphene is 71.5 % and the selectivity of the main product is 96.8 %.
出处
《生物质化学工程》
CAS
2007年第5期39-41,共3页
Biomass Chemical Engineering
关键词
莰烯
乙醇
异龙脑基乙醚
camphene
ethanol
isobornyl ethyl ether
