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紫外荧光测二氧化硫浓度系统研究 被引量:4

Detector for the Concentration of Sulfur Dioxide Based on Ultraviolet Fluorescence Method
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摘要 利用二氧化硫的多波长受激发的光学现象,设计双光源多波长激发紫外荧光法的二氧化硫浓度测量系统.阐述了多波长激发紫外荧光的原理和双光路补偿方法,与单色光激发荧光测量方法相比较,具有灵敏度高、分辨力强的特点.通过分别对流量为250mL/min、500mL/min含量二氧化硫样本气体,应用两种方法实测、验证了结论的正确性,并给出了新方法的实验数据和曲线.利用嵌入式系统和Internet,设计了实现网络化监测系统达到了远程监测目的. Baseed on considering the phenomenon of multi-wavelength excitation, a monitored control system for SO2 concentration with double lights source was designed. The principle of multi-wavelength excitation with double light ways was expounded and it was used as a compensating method to reduce error. To compare it with the monochrome light excitation, this method shows higher sensitivity and finer resolution. Two methods were applied separately to measure the curves of flow velocity 250 mL/min and 450 mL/min to the sulfur dioxide density ,which verified the accuracy of theoretical calculation from the new experimental data and curves of this method. Making use of the embedded system and INTERNER, a network system was designed to attain the perpose of a remote monitored control system for SO2.
出处 《传感技术学报》 CAS CSCD 北大核心 2007年第3期497-501,共5页 Chinese Journal of Sensors and Actuators
关键词 二氧化硫监测 紫外荧光法 远程监测 RTOS The monitoring of sulfur dioxide ultraviolet fluorescence method remote monitoring RTOS
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参考文献8

  • 1H.Okabe.Fluorescence and Prodissociation of Sulfur Dioxide[J].J Amer Chem Soc.1971,(93):7095709.
  • 2J.D.Bradshaw,M.O.Rodgers,D.D.Davis,Single Photon Laser-Induced Fluorescence Detection of NO and SO2 for Atmospheric Conditions of Composition and Pressure[J].AppOpt.1998,(21):2493250.
  • 3P.Warneck,F.F.Marmo,J.O.Sullivan.Ultraviolet Absorption of SO2[J].J Chem Phys.1996,(40):1132-1133.
  • 4H.Okabe,P.L.Splitstone,J.J.Ball Ambient and Source SO Detector Base on a Fluorescence Method[J].Journal of the Air Pollution Control Association.1998,(23):514-516.
  • 5Model 43C Pulsed Fluorescence SO2 Analyser Instruction Manual[J],Thermo Environmental Instruments Inc.
  • 6饶明辉,何振江,杨冠玲,艾锦云.大气二氧化硫浓度的光学测定方法[J].环境工程学报,2004(2):86-89. 被引量:5
  • 7TR.Minnich,R.L.Scotto,R.H.Kagann.Optical Remote Sensors Ready to Tackle Superfund,RCRA Emissions Monitoring Tasks[J].Hazmat World.1998,(3):42.
  • 8M.R.Dobber et al.,Ozone Monitoring Instrument Calibration[J],IEEE.Trans.Geosci.Remote Sens.2006,(5):1209-1238.

二级参考文献16

  • 1吴凤武,等.硫脲的化学发光分析研究[J].分析科学学报,2000,16(6):249-252.
  • 2[5]Dasgupta P. K., Kat S. Design and development of a system to measure ambient levels of hydrogen sulfide. Anal. Chem.,1995,69: 3853 ~ 3860
  • 3[6]N. Ekkad, C. O. Huber. Oxidative coulometric trace determination of sulphur in hydrocarbons. Chem. Acta, 1996,13(6) :458~ 463
  • 4[7]Krochmal D., Kalina A. A method of nitrogen dioxide and sulphur dioxide determination in amibient air by use of passive samplers and chromatography. Atmos. Environ., 1997, 31:3473 ~ 3479
  • 5[8]W. L. Crider. Methane composition of urban atmospheres.Anal. Chem. ,1965. ,37: 1770 ~ 1773
  • 6[10]Jules Duchesne B. Rosen. Contribution to the study of electronic spectra of bent triatomic molecules. Journal of Chemical Physics, 1947,15(9) :631 ~ 644
  • 7[11]D. Golomb, K. Watanabe, F. Fmarmo. Collection of sulfur doixide on membrane filters. Journal of Chemical Physics,1962,36(4) :958 ~ 960
  • 8[12]H.Okabe. Fluorescence and prodissociation of sulfur dioxide.Journal of the American Chemical Society, 1971,93: 7095 ~7097
  • 9[14]Hideo Okabe, P. L. Splitstone, J. J. Ball. Ambient and source SO2 detector based on a fluorescence method. Journal of the Air Pollution Control Association, 1973,23(10) :514 ~516
  • 10[15]S.S. Colier,Akira Morikawa,D. H. Slater, et al. Ultraviolet absorption of SO2: Dissociation of SO2. Journal of the American Chemical Society, 1970,92:217 ~ 218

共引文献4

同被引文献31

  • 1饶明辉,何振江,杨冠玲,艾锦云.大气二氧化硫浓度的光学测定方法[J].环境工程学报,2004(2):86-89. 被引量:5
  • 2Vogt R,Crutzen P J,Sandar R. A Mechanism for Halogen Release from Sea-Sahaerosol in the Remote Marine Boundary Layer [ J ]. Nature, 1996:383:327.
  • 3任慧敏.电化学分析[M].北京:化学工业出版社,1997:58-59.
  • 4Galle B, Oppenheimer C. Geyer A, et al. A Miniaturized Ultraviolet Spectrometer for Remote Sensing of SO2 Fluxes: A New Tool for Volcano Surveillance [ J ]. Journal of Volcanology and Geoihemml Research ,2003,119:241-254.
  • 5孙永跃.机动车尾气检测仪紫外差分算法研究与软件设计[D].天津:天津理工大学,2009:20-31.
  • 6EKKAD N. Oxidative coulometric trace determination of sulphur in hydrocarbons[J]. Chem Acta, 1996,13(6):458.
  • 7H OKABE. Fluorescence and prodissociation of sulfur dioxide[J]. J Amer Chem Soc,1971,93:705-709.
  • 8J D BRADSHAW, M O RODGERS,D DDAVIS.Single photon laser induced fluorescence detection of NO and SO2 for atmospheric conditions of composition and pressure[J].Appopt,1998,(21):249-250.
  • 9黎学明,王力春,杨建春,陈伟民.二氧化硫监测的光纤传感方法研究[J].光子学报,2008,37(1):51-55. 被引量:3
  • 10酸雨控制区和二氧化硫污染控制区划分方案[J].环境保护,1998,26(3):7-10. 被引量:35

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二级引证文献6

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