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悬浮态纳米TiO_2光催化降解喹啉的研究 被引量:4

Study on the Photocatalytic Degradation of Quinoline by the Suspended TiO_2 Nanoparticles
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摘要 采用Degussa P25 TiO2为光催化剂,在紫外光的照射下考察了有无空气、P25 TiO2催化剂用量、喹啉初始浓度、pH值及氯离子对光催化降解过程的影响。实验结果表明:空气促进喹啉和总有机碳的降解率,喹啉初始浓度越低,光催化降解过程越充分,P25 TiO2催化剂适宜浓度为0.70g/L,碱性环境下有利于喹啉的降解,pH=8.38时总有机碳的降解率达到94.47%,随着氯离子掺杂浓度的提高,总有机碳的降解率逐步下降。 The effects of air or no air, P25 TiO2 catalyst weight, feed concentration of quinoline, pH value and chlorine ion concentration using Degussa P25 titanium dioxide as the photo-catalyst and ultraviolet radiation on the process of photocatalytic degradation were investigated. The experimental results showed that air accelerates the degradation rate of quinoline and TOC. The lower the feed concentration of quinoline is, the more sufficient the photocatalytic degradation process is. The suitable concentration of P25 TiO2 is 0.70 g/L. Quinoline is easier to degrade under the condition of alkaline environment when the pH value is 8.38 ,the TOC degradation rate achieve 94.47 %. With the increasing concentration of chlorine ion, the degradation rate of TOC decreases step by step.
出处 《净水技术》 CAS 2007年第4期44-47,76,共5页 Water Purification Technology
关键词 二氧化钛 喹啉 总有机碳 光催化 降解 titanium dioxide quinoline total organic carbon photocatalysis degradation
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参考文献9

  • 1Fujishima A,Honda K.Eletrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,37(1):238-245
  • 2M.A.Barakat,Y.T.Chen,C.P.Huang.Removal of toxic cyanide and Cu(Ⅱ) ions from water by illuminated TiO2 catalyst[J].Applied Catalysis B:Environmental,2004,53(1):13-30
  • 3Nader M.Al-Bastaki.Performance of advanced methods for treatment of wastewater:UV/ TiO2,RO and UF[J].Chemical Engineering and Processing,2004,43(7):935-940
  • 4Taicheng An,Wenbing Zhang,Xianming Xiao,et al.Photoelectrocatalytic degradation of quinoline with a novel three-dimensional electrode-packed bed photocatalytic reactor[J].Journal of Photochemistry and Photobiology A:Chemistry,2004,161:233-242
  • 5R.Franke,C.Franke.Model reactor for photocatalytic degradation of persistent chemicals in ponds and waste water[J].Chemosphere,1999,39(15):2651-2659
  • 6Shinji Kato,Yuji Hirano,Misao Iwata,et al.Photocatalytic degradation of gaseous sulfur compounds by silver-deposited titanium dioxide[J].Applied Catalysis B:Environmental,2005,57(2):109-115
  • 7M.H.Priya,Giridhar Madras.Photocatalyti degradation of nitrobenzenes with combustion synthesized nano-TiO2[J].Journal of Photochemistry and Photobiology A:Chemistry,2006,178:1-7
  • 8Rosario Enriquez,Pierre Pichat.Interactions of humic acid,quinoline,and TiO2 in water in relation to quinoline photocatalytic removal[J].Langmuir,2001,17:6132-6137
  • 9Pierre Pichat.Photocatalytic degradation of aromatic and alicyclic pollutants in water:by-products,pathways and mechanisms[J].Water Science and Technology,1997,35(4):73-78

同被引文献30

  • 1乔世俊,赵爱平,徐小莲,赵慧宏,吴仁铭.二氧化钛光催化降解处理氨氮废水[J].环境科学研究,2005,18(3):43-45. 被引量:32
  • 2景长勇,崔建升,冯辉,吴韶梅.电催化氧化法处理阴离子表面活性剂废水[J].化工环保,2005,25(5):368-371. 被引量:11
  • 3林根仙,何蓉,郭俊文.氨氮对循环冷却水系统的危害与对策[J].工业水处理,2006,26(5):82-84. 被引量:23
  • 4王嘉,周涛,任大军,陆晓华.喹啉的微波辅助光催化氧化降解研究[J].环境保护科学,2007,33(2):21-24. 被引量:7
  • 5Fujishima A , Honda K. Electrochemical photolysis of water at a semicondutor electrode [ J ]. Nature, 1972, 238 (5358) :37 - 38.
  • 6Baea T H, Kimb I C, Tak T M. Preparation and characterization of fouling - resistant TiO2 self - assembled nanocomposite membranes [J]. J Membr Sci, 2006, 275 (5):1 -5.
  • 7Subhrakanti Saha,Rajib Mistri ,Ray B C. Determination of pyridine, 2 -picoline, 4 -picoline and quinoline from mainstream cigarette smoke by solid-phase extrac- tion liquid chromatography/electrospray ionization tandem mass spectrometry [ J ]. J Chromatogr A, 2010, 1217(3) :307 -311.
  • 8Li Miao, Feng Chuanping, Hu Weiwu, et al. Electrochemical degradation of phenol using electrodes of Ti/RuO2 - Pt and Ti/IrO2 - lot[J]. J Hazard Mater ,2009, 162 (1) : 455 -462.
  • 9Chen Guohua, Chen Xueming. Electrochemical Behavior of Novel Ti/IrOx - Sb2 05 - SnO2 Anodes [ J ], J Phy Chem B,2002,106 ( 17 ) :4364 - 4369.
  • 10Alexei N , John K. Parameters affecting the homogeneous and heterogeneous degradation of quinoline solutions in light-activated processes [ J ]. J Photochem Photobiol A: Chemistry, 1997,110 (2) : 149 - 150.

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