期刊文献+

Aerosol-OT在硝基乙胺中形成胶束的热力学研究

THERMODYNAMICS OF AOT MICELLE FORMATION IN ETHYLAMMONIUM NITRATE
在线阅读 下载PDF
导出
摘要 用表面张力法研究了AOT在硝基乙胺中形成的胶束聚集体,得到了在不同温度下AOT在硝基乙胺中形成胶束的临界胶束浓度,并根据胶束的两相模型的热力学方程得到了胶束形成的热力学参数,结果表明溶液中胶束的形成是一个自发,吸热,熵增大的过程。 AOT micelle formation in ethylammonium nitrate (an ionic liquid) was investigated by surface tension measurement in this paper and the critical micelle concentrations (cmc) of AOT in ethylammonium nitrate at different temperatures were obtained. The thermodynamic parameters of micelle formation were obtained according to the twophase thermodynamic model. The results suggested that the micelle formation of AOT in ethylammonium nitrate was a spontaneous, endothermal and entropy - increasing process.
出处 《武汉工业学院学报》 CAS 2007年第3期45-48,共4页 Journal of Wuhan Polytechnic University
基金 湖北省自然科学基金项目(2006ABA271)
关键词 胶束 热力学 离子液体 micelles thermodynamics ionic liquids
  • 相关文献

参考文献14

  • 1Welton T.Room-Temperature Ionic Liquids.Solvents for Synthesis and Catalysis[J].Chem Rev,1999,99:2071-2084.
  • 2Anderson J L,Ding J,Welton T,et al.Characterizing Ionic Liquids On the Basis of Multiple Solvation Interactions[J].J Am Chem Soc,2002,124:14247-14254.
  • 3Kazarian S G,Briscoe B J,Welton T.Combining Ionic Liquids and Supercritical Fluids:in Situ ATR-IR Study of CO2 Dissolved in Two Ionic Liquids at High Pressures[J].Chem Commun,2000,2047-2048.
  • 4Anderson J L,Pino V,Hagberg E C,et al.Surfactant Solvation Effects and Micelle Formation in Ionic Liquids[J].Chem Commun,2003,2444-2445.
  • 5Binks B P,Dyab A K F,Fletcher P D I.Surfactant Solvation Effects and Micelle Formation in Ionic Liquids[J].Chem Commun,2003,2540-2541.
  • 6Nakashima T,Kimizukua N.Interfacial Synthesis of Hollow TiO2 Microsp -heres in Ionic Liquids[J].J Am Chem Soc,2003,125:6386-6387.
  • 7Heintz A,Kulikov D V,Verevkin S P.Thermodynamic Properties of Mixtures Containing Ionic Liquids,1.Activity Coefficients at Infinite Dilution of Alkanes,Alkenes,and Alkylbenzenes in 4-Methyl-n-butylpyridinium Tetrafluoroborate Using Gas-Liquid Chromatography[J].J Chem Eng Data,2001,46:1526-1529.
  • 8Heintz A,Lehmann J K,Wertz C.Thermodynamic Properties of Mixtures Containing Ionic Liquids.3.Liquid-Liquid Equilibria of Binary Mixtures of 1-Ethyl-3-methylimidazolium Bis (trifluoromethylsulfonyl) imide with Propan-1-ol,Butan-1-ol,and Pentan-1-ol[J].J Chem Eng Data,2003,48:472-474.
  • 9Bowers J,Butts C P,Martin P J,et al.Aggregation Behavior of Aqueous Solutions of Ionic Liquids[J].Langmuir,2004,20 (6):2191-2198.
  • 10Anderson J L,Ding J,Welton T.et al,Characterizing Ionic Liquids On the Basis of Multiple Solvation Interactions[J].J Am Chem Soc,2002,124:14247-14254.

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部