摘要
采用水热法并以乙二胺为模板剂合成了具有微孔结构的钨磷多金属氧酸盐(C2N2H10)2[H2P2W18O62].8H2O.通过元素分析、等离子发射光谱、X射线单晶衍射等进行了结构表征,并用电化学方法对标题化合物的电化学性质进行了研究.
A microporous tungsten polyoxometalate, （C2N2H10）2[H2P2W18O62]·8H2O has been synthesized hydrothermally with ethylenediamine as the structure-directing agent,and the title compound has been characterized by elemental analysis and single-crystal X-ray structure analysis. The electrochemistry property of the compound has been investigated by electrochemistry method.
出处
《分子科学学报》
CAS
CSCD
2007年第4期276-280,共5页
Journal of Molecular Science
基金
内蒙古自然科学基金资助项目(20001301)
内蒙古自治区人才开发基金资助项目(20061012)
关键词
水热合成
晶体结构
多金属氧酸盐
电化学性质
hydrothermal synthesis
cystal structure
plyoxometalate
electrochemical behavior
