摘要
共轭型含硫聚西佛碱是一新颖聚合物,本征导电率为3.4×10^(-11)S/cm,当该聚合物以碘、溴、五氯化锑和萘钠等掺杂后,导电性可进一步提高。碘掺杂该聚合物后导电性可达10^(-3)S/cm,且具有良好的耐候稳定性和高掺杂度特点。研究了掺杂材料的耐温性及各种试制对其导电性的影响。
Sulfur containing Poly Schiff Base (PS-4) is a new conjugated Polymer with conductivity of 3.4×10^(-11)S/cm. When the polymer was doped with I_2, Br_2, SbCl_5 and Sodium naphthalide, etc, it was found that the conductivity could be increased. The iodine dopes PS-4 has conductivity of 10^(-3) s/cm and good environmental stability as well as high dopant level. The influenc of temperature and different solvents on comductivity of the doped material have also been investigated.
出处
《功能高分子学报》
CAS
CSCD
1990年第3期185-191,共7页
Journal of Functional Polymers
关键词
聚西佛碱
掺杂
导电率
Poly Schiff Base, Doping, Conductivity, Properties
