摘要
用全相对论量子力学方法计算NⅢ,OⅣ和FⅤ的1s2s2p36S0-1s2s2p23s6P的跃迁精细结构。
A fully reativistic Dirac-Fock method with Breit and QED Correction has been used to calculate the optical fransitions of doubly-excited sixtet states 1s2s2p 3 6S 0-1s2s2p 23s 6P for NⅢ, OⅣ and FⅤ, which are in quite good agreement with experiments. The suggestion that the nonrelativistic corretation effects are divided into dynamical and nondynamical correlations are now extended into relativistic quantum mechanics. It is found that dynamical correlation, particularly, Fermi correlation is remarkable for high spin ions.
出处
《原子与分子物理学报》
CAS
CSCD
北大核心
1997年第1期56-60,共5页
Journal of Atomic and Molecular Physics