摘要
本文研究了高锰酸钾对烯烃氧化的反应机理．研究结果表明，高锰酸钾对烯烃的氧化是分步进行的，首先高锰酸钾与烯烃反应生成环型的高锰酸酯中间体，此中间体易在反应条件下分解为羧酸或酮．文中主要考察了酸度介质及取代基对此氧化反应的影响，给出了该氧化反应的一些规律性。
In this paper,the mechanism of potassium permanganate oxidadtion of alkene has been studied.The results show that the mechanism of this reaction involves two steps,the first,a cyclic intermediate is formed by the reaction of potassium permanganate with alkene.then this intermediate will decompose to form carborylic acids and ketones.The effect of acidity of solution and substiuted group of reactant on the oxidation of alkene by permanganate ion is also discussed.
出处
《淮北煤师院学报（自然科学版）》
1997年第1期37-41,共5页
Journal of Huaibei Teachers College(Natural Sciences Edition)
关键词
高锰酸钾
氧化反应
烯烃
potassium permanganate oxidation alkene reaction mechanism.
