摘要
借助似谐振子模型和统计方法,对玻璃态链状均聚物作了一般讨论,并推出比热和线膨胀系数的一般表达式。最后,以PS为例,把理论值与实验值作了比较,结果是令人满意的。
This paper gives the general discussion for chain homopolymers by quasi-harmonic oscillator model and statistical method. It obtain an expression of coefficient of linear expansion. The values of calculation are in good agreement with experiment values. The result is satisfying.
出处
《高分子学报》
SCIE
CAS
CSCD
北大核心
1990年第5期513-519,共7页
Acta Polymerica Sinica
关键词
均聚物
玻璃态
线膨胀系数
比执
Mer, Equivalent atom, Quasi-harmonic oscillator, Homopolymer, Glassy state, Specific heat, Linear expansion
