摘要
综述了不同氧源与丙烯环氧化反应的研究新进展。主要包括:氢氧原位制备过氧化氢丙烯环氧化,直接以分子氧为氧化剂的光诱导环氧化反应以及以臭氧和一氧化二氮为氧化剂的研究。指出开发活性高、选择性好的催化剂是解决问题的关键,并对其应用前景进行了讨论。
This paper reviews the new research progress of epoxidation of propylene with different oxidants. It includes propylene epoxidation with hydrogen peroxide in-situ synthesized using hydrogen and oxygen, photoepoxidation of propylene and oxygen and reactions with ozone and nitrous oxide as oxidants. It indicates that the major task is development of active and selective catalysts. The application prospect of new processes is also discussed.
出处
《化工进展》
EI
CAS
CSCD
北大核心
2007年第6期769-773,共5页
Chemical Industry and Engineering Progress
基金
国家973资助项目(No.2006CB202508)
关键词
丙烯
环氧化
环氧丙烷
催化剂
propylene
epoxidation
propyleneoxide
catalyst