Thermal Behavior and Non-isothermal Kinetics of the Polyoxometalate of Ciprofloxacin with Tungstophosphoric Acid 被引量：1

Thermal Behavior and Non-isothermal Kinetics of the Polyoxometalate of Ciprofloxacin with Tungstophosphoric Acid

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摘要 The polyoxometalate （CPFX-HCl）3H3PW12O40·.8H2O was prepared and characterized by elemental analysis, IR spectra and TG-DTA-DTG. The thermal decomposition mechanism and non-isothermal kinetic parameters of the polyoxometalate were obtained from the analysis of TG-DTG data using the Achar equation, Coats-Redfern equation （CR）, Madhusudanan-Krishnan-Ninan equation （MKN） and Horowitz-Metzger equation （HM）. And their mathematical expressions of the kinetic compensation effect were also calculated. The polyoxometalate （CPFX-HCl）3H3PW12O40·.8H2O was prepared and characterized by elemental analysis, IR spectra and TG-DTA-DTG. The thermal decomposition mechanism and non-isothermal kinetic parameters of the polyoxometalate were obtained from the analysis of TG-DTG data using the Achar equation, Coats-Redfern equation （CR）, Madhusudanan-Krishnan-Ninan equation （MKN） and Horowitz-Metzger equation （HM）. And their mathematical expressions of the kinetic compensation effect were also calculated.

作者汪敦佳

机构地区 Hubei Key Laboratory of Bioanalytical Technique

出处《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2007年第2期240-244,共5页 武汉理工大学学报（材料科学英文版）

基金 the Natural Science Foundation of the Educational Commission of Hubei Province(No.J200522002 and Z200622001)

关键词 non-isothermal kinetics thermal behavior POLYOXOMETALATE CIPROFLOXACIN TG-DTA-DTG non-isothermal kinetics thermal behavior polyoxometalate ciprofloxacin TG-DTA-DTG

分类号 O631.3 [理学—高分子化学]

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Journal of Wuhan University of Technology(Materials Science)

2007年第2期

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