摘要
用XPS、UPS、ESR研究了Ni－ZrO_2复合层中基质金属Ni与ZrO_2微粒间的轨道相互作用，建立了相应的分子模型。
The atomic orbital interaction existing in the interface between matrix metal Ni and ZrO_2 particles was investigated by XPS, UPS and ESR, and corresponding orbital interaction molecular model was proposed. The high electrocatalytical activity of Ni--ZrO2 composite plating can be explained reasonably by the model. Some new ideas about the structure among phases in composite material and composite electrodeposition have also been proposed in the paper.
出处
《材料研究学报》
EI
CAS
CSCD
北大核心
1997年第2期143-147,共5页
Chinese Journal of Materials Research
关键词
复合镀层
界面结构
轨道相互作用
析氢
Ni-ZrO_2 composite plating interfacial structure orbital interaction electrocatalysis hydrogen evolution
