摘要
研究了甲醇与环氧丙烷在碱性催化剂ＴＡ存在下均相合成丙二醇甲醚的过程。在甲醇与环氧丙烷的配比为３∶１～５∶１（ｍｏｌ），催化剂使用量为０．５％～１．０％，反应温度６０～１２０℃条件下，环氧丙烷转化率在９９％以上，丙二醇甲醚的选择性在９５％以上。对该反应的动力学研究表明，反应为一连串平行反应，并建立了相应的动力学模型。
A process of reacting propylene oxide with methanol using basic catalyst TA is investigated. Under the reaction conditions of the methanol/PO molar ratio between 3∶1￣5∶1,the temperature beteen 60￣120℃ and the amount of TA between 0.5%￣1.0%, the conversion of propylene oxide is more than 99%, and the selectivity of PM is higher than 95%. The research of reaction kinetics shows that the reaction is a consecutive parallel one. Reaction kinetic model has been established.
出处
《华东理工大学学报（自然科学版）》
EI
CAS
CSCD
北大核心
1997年第1期39-44,共6页
Journal of East China University of Science and Technology
关键词
均相反应
丙二醇甲醚
催化
合成
催化剂
homogeneous reaction
methanol
propylene oxide
PM
kinetics
