期刊文献+

油包水高内相比乳液模板法制备聚苯乙烯多孔材料 被引量:2

Preparation of Porous Materials Using Water-in-oil High Internal Phase Emulsions as Templates
原文传递
导出
摘要 以油包水高内相比乳液模板法制备了聚苯乙烯多孔材料,材料的泡孔直径5~35um,通道直径2.9~6um。探讨和分析了乳化剂、非反应性溶剂、分散相(水)以及有机相中共聚组分的用量对聚苯乙烯多孔材料断面形态的影响。结果表明,通过控制原料配比和反应条件可以达到控制泡孔和通道直径的目的,从而制得特定泡孔和通道尺寸的多孔材料。 The porous polystyrene materials were prepared using water-in-oil high internal phase emulsions (HIPEs) as templates. The void diameter was between 5 -35um, and the diameter of channel was 2.9 -6um. The factors such as the content of emulsifier, non-reactive solvent, disperse phase (water) and amount of copolymerizing components in organic phase influencing on the features of the morphology of porous polystyrene material section were discussed and analyzed. The results showed that the porous materials with special void and channel could be prepared by controlling material ratio and processing conditions.
出处 《精细与专用化学品》 CAS 2007年第9期17-20,共4页 Fine and Specialty Chemicals
关键词 油包水高内相比乳液模板 多孔材料 聚苯乙烯 water-in-oil high internal phase emulsion template porous material polystyrene
  • 相关文献

参考文献22

  • 1[1]Busby W,Cameron N R,Jahoda C A B.Emulsion-derived forms (poly-HIPEs) containing poly (ε-caprolactone) as matrixes for tissue engineering[J].Biomacromolecules,2001,2:154~164
  • 2[2]Akay G,Birch M A,Bokhari M A.Microcellular polyHIPE polymer supports osteoblast growth and bone formation in vitro[J].Biomaterials,2004,25:3991~4000
  • 3[3]Hayman M W,Smith K H,Cameron N R,et al.Growth of human stem cell-derived neurons on solid three-dimensional polymers[J].Biochem Biophys Methods,2005,62:231~240
  • 4[4]Krajnc P,Brown J F,Cameron N R.Monolithic scavenger resins by amine functionalizations of poly(4-vinylbenzylchloride-co-diviyl benzene)polyHIPE materials[J].Org Lett,2002,4:2497~2500
  • 5[5]Laurence Moine,Herve Deleuze,Bernard Maillard.Preparation of high loading polyHIPE monoliths as scavengers for organic chemistry[J].Tetrahedron Letters,2003,44:7813~7816
  • 6[6]Ottens M,Leene G,Beenackers A,et al.Kine-tics,catalysis,and reaction engineering[J].Ind Eng Chem Res,2000,39:259-266
  • 7[7]Herve Deleuze,Bernard Maillard.Development of new ultraporous polymers as support in organic synthesis[J].Bioorfanic and Chemistry Letters,2002,12:1877-1880
  • 8[8]Bhumgara Z.Polyhipe foam materials as filtration media[J].Polymeric foam filter media,1995,245~251
  • 9[9]Kabalnov A S,Pertsov A V,Shchukin E D.Ostwald ripening in emulsions:I.Direct observations of Ostwald ripening in emulsions[J].J Collid Interface Sci,1987,118:590~597
  • 10[10]Hainey P,Huxham I M,Rowatt B,et al.Synthesis and ultrastructural studies of styrene-divinylbenzene polyhipe polymers[J].Macromolecules,1991,24:117~121

同被引文献23

引证文献2

二级引证文献5

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部