摘要
The hydrothermal reaction of 1,2-dicyanobenzene with NaN3 in the presence of Cd（NO3）2 affords a novel 2D cadmium tetrazolyl-benzoate, {Cd（tzbz）（H2O）}n （H2tzbz is 2-（5-tetrazolyl）-benzoate）. The tzbz ligand is generated in situ through the [2＋3] Sharpless cycloaddition reaction and hydrolyzation. Its crystal structure was determined by single-crystal X-ray diffraction method. The crystal crystallizes in the orthorhombic system, space group Pbca with a = 9.6659（19）, b = 7.6366（15）, c = 25.964（5）A, V= 1916.5（7）A^3, Z= 8, Mr = 318.57, Dc = 2.208 g/cm^3, F（000） = 1232 and p = 2.276 mm^-1. The Cd（Ⅱ） atom is coordinated by four tzbz ligands and one water molecule to form a severely distorted pentangle bipyramid. While each tzbz ligand connects to four Cd（Ⅱ） atoms in a μ4-η1, η, η1, η1, η1 coordination mode to construct a 2D architecture of the title complex. Additionally, the title complex exhibits strong fluorescence at room temperature in the solid state.
The hydrothermal reaction of 1,2-dicyanobenzene with NaN3 in the presence of Cd（NO3）2 affords a novel 2D cadmium tetrazolyl-benzoate, {Cd（tzbz）（H2O）}n （H2tzbz is 2-（5-tetrazolyl）-benzoate）. The tzbz ligand is generated in situ through the [2＋3] Sharpless cycloaddition reaction and hydrolyzation. Its crystal structure was determined by single-crystal X-ray diffraction method. The crystal crystallizes in the orthorhombic system, space group Pbca with a = 9.6659（19）, b = 7.6366（15）, c = 25.964（5）A, V= 1916.5（7）A^3, Z= 8, Mr = 318.57, Dc = 2.208 g/cm^3, F（000） = 1232 and p = 2.276 mm^-1. The Cd（Ⅱ） atom is coordinated by four tzbz ligands and one water molecule to form a severely distorted pentangle bipyramid. While each tzbz ligand connects to four Cd（Ⅱ） atoms in a μ4-η1, η, η1, η1, η1 coordination mode to construct a 2D architecture of the title complex. Additionally, the title complex exhibits strong fluorescence at room temperature in the solid state.
基金
the State Key Laboratory of Structural Chemistry, the 973 program (2006CB932900)
the NNSFC (20673118, 20333070, 90206040 and 90406024)
NSF of Fujian Province (2006J0014, 2004HZ01-1, and 2005HZ01-1)
