摘要
ＰＣｌ５与Ｃｌ３ＣＣＨＯ加成后在低温下通入干燥的Ｈ２Ｓ（ｇ），可制得Ｃｌ３ＣＣＨＣｌＯＰ（Ｓ）Ｃｌ２（１），（１）依次与取代苯酚、胺反应合成了１２个具有生物活性的标题化合物．用ＩＲ、ＮＭＲ、ＭＳ和元素分析对其结构进行了表征．并讨论了合成方法、波谱性质和生物活性的规律．结果表明该类硫逐磷酰胺的抑制植物生长活性较高。
Twelve new O substituted phenyl O tetrachloroethyl phosphoramidothioates were synthesized. The title compounds have been characterized by IR, MS, NMR and elementary analysis. Their biological activities were tested. The results showed these phosphoramidothioates are better herbicides, and these phosphorothioates are better insecticides.
出处
《湖北大学学报（自然科学版）》
CAS
1996年第2期150-154,共5页
Journal of Hubei University：Natural Science
基金
国家教委科研基金
