摘要
A metal-organic coordination polymer [Co（phen）（BDC）（H20）]n·0.5nH2BDC （H2BDC = terephthahc acid, phen = 1,10-phenanthrohne） has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. The complex crystallizes in triclinic, space group Pi with a = 9.771（3）, b =10.739（3）, c = 11.249（4）A, α = 75.946（3）, β = 65.306（3）, γ = 86.073（4）°, V = 1039.6（6）A^3, C24H17CON2O7, Mr= 504.33, Dc = 1.611 g/cm^3,μ（MoKα） = 0.878 mm^-1, F（000） = 516, Z= 2, the final R = 0.0547 and wR = 0.1138 for 2916 observed reflections （I 〉 2σ（I））. It exhibits a one-dimensional zigzag chain-like structure.
A metal-organic coordination polymer [Co（phen）（BDC）（H20）]n·0.5nH2BDC （H2BDC = terephthahc acid, phen = 1,10-phenanthrohne） has been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, TG and single-crystal X-ray diffraction. The complex crystallizes in triclinic, space group Pi with a = 9.771（3）, b =10.739（3）, c = 11.249（4）A, α = 75.946（3）, β = 65.306（3）, γ = 86.073（4）°, V = 1039.6（6）A^3, C24H17CON2O7, Mr= 504.33, Dc = 1.611 g/cm^3,μ（MoKα） = 0.878 mm^-1, F（000） = 516, Z= 2, the final R = 0.0547 and wR = 0.1138 for 2916 observed reflections （I 〉 2σ（I））. It exhibits a one-dimensional zigzag chain-like structure.
基金
The project was supported by the Education Office of Jilin Province (No. 0047)
