摘要
报道了溴化十六烷基三甲胺CTMAB与乳剂OP共存时,在硫酸、盐酸介质中,用苯芴酮分光光度法测定铜合金中锡的研究.该混配颜色化合物的λmax 505nm,εmax 5.24×106 L·mol-1cm-1,锡的检量范围0~50μgmL-1,服从朗伯—比尔定律,具有较高的灵敏度、选择性,重现性、稳定性也较好,适用于工厂中铜合金锡的检测.
The multi-ligand chromogenic reaction system of Sn(II)phenylflurone CTMAB OP and the method of spectrophotometric determination are studied.The maximum absorption at 505 nm and the molar absorptivity of complex are 5.24×10 6 L·mol -1 ·cm -1 .The examination range of Sn is found out to be O~50~μg·ml -1 .The application of the spectrophotometric method to imdustrial production is also discussed. ①
出处
《四川师范学院学报(自然科学版)》
1996年第4期22-25,共4页
Journal of Sichuan Teachers College(Natural Science)