摘要
A complex, NiL(Phen)2(H2O)5 (Phen=1,10 phenanthroline; L=malonate), has been synthesized and chara-cterized. Single crystal X-ray structural determination has been carried out for the complex, the crystal is triclinic system, space group P1 with a=1.042 4(4) nm, b=1.061 2(4) nm, c=1.303 8(5) nm, α=85.784(4)°, β=77.232(3)°, γ=72.879(4)°, Mr=611.24, V=1.344 2(8) nm3, Z=2. In this complex, the central metal Ni(Ⅱ) atom is in distorted octa-hedron coordination environment. The molecule is extended to 2D network by the intermolecular π-π stacking interaction.
A complex, NiL（Phen）2（H2O）5 （Phen=1,10 phenanthroline; L=malonate）, has been synthesized and characterized. Single crystal X-ray structural determination has been carried out for the complex, the crystal is triclinic system, space group P1^ with a=1.0424（4） nm, b=1.061 2（4） nm, c=1.303 8（5） nm, α=85.784（4）°, β=77.232（3）°, γ= 72.879（4）°, Mr=611.24, V=1.344 2（8） nm^3, Z=2. In this complex, the central metal Ni（Ⅱ） atom is in distorted octahedron coordination environment. The molecule is extended to 2D network by the intermolecular π-π stacking interaction. CCDC： 278766.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2007年第3期513-516,共4页
Chinese Journal of Inorganic Chemistry
