摘要
全氟丁基锂与醛、酮、酰氯和酯反应生成全氟丁基取代醇和酮。在超声作用下，全氟丁基碘与镁作用后也可与醛或酮反应。以全氟丁基取代叔醇的脱水和全氟丁基取代仲（叔）醇的乙酸酯热解后得到全氟丁基取代烯烃。
A series of perfluorobutyl substituted alcohols and ketones were prepared by nucleophilic addition of carbonyl compounds by C_4F_9I with C_4H_9 Li or with Mg under ultrasonic irradiation.The perfluorobutylated olefins were produced via dehydration of the perfluorobutylated tertiary alcohols and by flash pyrolysis of the acetates of the corresponding perfluorobutyled secondary or tertiary alcohols.
出处
《华东理工大学学报（自然科学版）》
CAS
CSCD
1996年第3期356-361,共6页
Journal of East China University of Science and Technology
关键词
全氟丁基化
醇
酮
合成
烯烃
perfluorobutylated
alcohols
ketones
olefins
synthesis
