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萘啶酮的单核和双核银配合物的合成与晶体结构(英文) 被引量：2

Synthesis and Structural Characterization of Mononuclear and Dinuclear Silver Complexes of Naphthyridinone
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摘要 合成了萘啶酮的单核和双核银配合物Ag2(L1)2(HL1=5,7-二甲基-1,8-萘啶-2-酮)(1)和[Ag(HL2)(PPh3)2]·2H2O(H2L2=1,8-萘啶-2,7-二酮)(2)。并通过元素分析,红外光谱及X-射线单晶衍射对其进行了结构表征。配合物1的晶体属单斜晶系,P1空间群。中心金属银为三配位T型几何构型,Ag-Ag间距离为0.2748(2)nm,具有强的Ag…Ag作用。配合物2的晶体属三斜晶系,P21/n空间群。银与1个氮原子及2个磷原子形成三配位结构。 Complex Ag2（L1）2 （HL1=5,7-dimethyl- 1,8-naphthyridin-2-one） （1） and [Ag（HL2）（PPh3）2]· 2H2O （H2L2= 1,8- naphthyridin-2,7-dione） （2） have been prepared and their structures were determined by X-ray diffraction. Ag2（L1）2 crystallizes in a monoclinic space P1. The Ag^＋ ion features a T-shaped tricoordinated geometry, being coordinated by two nitrogen atoms from two different L1 ligands and one from Ag... Ag interaction. The Ag... Ag bond distance is 0.274 8（2） nm showing some metallophilic interaction. [Ag（HL2）（PPh3）2] ·2H2O crystallizes in a triclinic space group P21/n. The Ag^＋ ion is tricoordinated by one N atom from L2 and two triphenylphosphine. CCDC： 608043, 1; 608044, 2.
作者 金首文 陈万芝 王大奇
机构地区 浙江大学化学系 聊城大学化学系
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2007年第2期270-274,共5页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金资助项目(No.20572096) 浙江省自然科学基金资助项目(No.R405066)
关键词 合成 萘啶酮 银配合物 晶体结构 synthesis naphthyridinone silver complex crystal structure
分类号 O614.122 [理学—无机化学]
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参考文献28

  • 1Berg A, Shuali Z, Asano-Someda M, et al. J. Am. Chem. Soc., 1999,121:7433-7434.
  • 2Pastemack R F, Caccam M, Keogh B, et al. J. Am. Chem., Soc., 1991,113:6835-6840.
  • 3Campbell K, Kuehl C J, Ferguson M J, et al. J. Am. Chem. Soc., 2002,124:7266-7277.
  • 4Papaefstathiou G S, MacGillivray L R. Angew. Chem. Int. Engl. Ed., 2002,41:2070-2073.
  • 5Schmidbaur H. Chem. Soc. Rev., 1995,24:391-400.
  • 6Koizumi T, Tanaka K. Inorg. Chim. A cta, 2004,357:3666-3672.
  • 7Munakata M, Maekawa M, Kitagawa S, et al. Inorg. Chim. Acta, 1990,167:181-188.
  • 8Griffith W P, Koh T Y, White A J P, et al. Polyhedron, 1995,14:2019-2025.
  • 9Oskui B, Sheldrick W S. Eur. J. Inorg. Chem., 1999:1325-1333.
  • 10Mintert M, Sheldrick W S. Inorg. Chim. Acta, 1995,236: 13-17.

同被引文献19

  • 1牛淑云,王茹,金晶,迟玉贤.配合物Cd_2(C_8H_7O_2)_4(phen)_2的合成、晶体结构和光物理性质[J].辽宁师范大学学报（自然科学版）,2006,29(1):58-61. 被引量：7
  • 2[4]ZHANG G Q,YANG G Q,MA J S.A novel luminescent metallomacrocycle assembled by silver nitrate and 1,3 bis (pyrrol-2-yl-methyleneamino) propane[J].Inorgan.Chem.Commun.,2004,7:994-997.
  • 3[6]CHEN W Z,LIU F H.Synthesis and characterization of oligomeric and polymeric silverimidazol-2-ylidene iodide complexes[J].J.Organomet.Chem.,2003,673:5-12.
  • 4[7]LI K H,HUANG G,XU Z T,et al.Distinct host-vip interaction and subdued fluorescence in a coordination network of 2,3,6,7,10,11-hexakis (phenylthio) triphenylene and silver (I) triflate[J].J.Solid State Chem.,2006,179:3688-3694.
  • 5[8]ZHANG L,LU X Q,ZHANG Q,et al.Coordination modes of diphosphines in silver (I)-diphosphine complexes mediated by 2,4,6-tri (2-pyridyl)-1,3,5-triazine (tptz)[J].Transition Met.Chem.,2005,30:76-81.
  • 6[9]YUE N L S,JENNINGS M C,PUDDEPHATF R J.Disilver (I) Macrocycles:Variation of Cavity Size with Anion Binding[J].Inorg.Chem.,2005,44:1125-1131.
  • 7[10]MELAIYE A,SIMONS R S,MILSTED A,et al.Formation of Water-Soluble Pincer Silver (I)-Carbene Complexes:A Novel Antimicrobial Agent[J].J.Med.Chem.,2004,47:973-977.
  • 8[11]LIU B,YUAN Q.Two novel linear arrangement d10 hexamers with isonicotinic acid:Structures,blue luminescent and semiconducting properties[J].Inorgan.Chem.Commun.,2005,8:1022-1024.
  • 9[12]XIE F T,BIE H Y,XU J Q,et al.Self-assembly of silver polymers based on exible isonicotinateligand at different pH values:syntheses,structures and photoluminescent properties[J].J.Solid State Chem.,2005,178:2858-2866.
  • 10ZHANG G Q, YANG G Q, MA J S. A novel luminescent metallomacrocycle assembled by silver nitrate and 1,3-bis(pyrrol-2-yl- methyleneamlno)propane[J]. Inorganic Chemistry Communications,2004,7:994-997.

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无机化学学报
2007年 第2期

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