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High-temperature oxidation behavior of Nb_(67-x)W_(15)Si_(18)Hf_x(x=0, 5 and 10) alloys 被引量:1

High-temperature oxidation behavior of Nb_(67-x)W_(15)Si_(18)Hf_x(x=0, 5 and 10) alloys
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摘要 The oxidation behaviors of Nb67-xW15Si18Hfx (x=0, 5, 10) alloys were studied at 1 250℃in air. It is found that the Nb67W15Si18 alloy has the best oxidation resistance among the three alloys; and Hf addition is harmful to the oxidation resistance of the Nb67W15Si18 alloy. The oxides formed on the Nb67W15Si18 alloy are mainly Nb12WO33 and NbO2, and that on the Nb62W15Si18Hf5 and Nb57W15Si18Hf10 alloys is Nb2O5. Effect of Hf on the oxidation behavior of the Nb67-xW15Si18Hfx alloys has been discussed based on microstructures and kinetics of oxidation. The oxidation behaviors of Nb67-xW15Si18Hfx (x=0, 5, 10) alloys were studied at 1 250 ℃ in air. It is found that the Nb67W15Si18 alloy has the best oxidation resistance among the three alloys; and Hf addition is harmful to the oxidation resistance of the Nb67W15Si18 alloy. The oxides formed on the Nb67W15Si18 alloy are mainly Nb12WO33 and NbO2, and that on the Nb62W15Si18Hf5 and Nb57W15Si18Hflo alloys is Nb2O5. Effect of Hfon the oxidation behavior of the Nb67-xW15Si18Hfx alloys has been discussed based on mierostructures and kinetics of oxidation.
出处 《中国有色金属学会会刊:英文版》 CSCD 2006年第A03期2009-2012,共4页 Transactions of Nonferrous Metals Society of China
基金 Project(50671002) supported by the National Natural Science Foundation of China
关键词 镍合金 高温氧化 抗氧化性 熔炼温度 Nb-Si based alloys Ni67-xW15Si18Hfx alloys high-temperature oxidation oxidation resistance oxide
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