期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

溅射腔气压对电极材料析氢活性的影响

Influnce of Sputtering Pressure on Hydrogen Evolution Reaction of Catalysis Electrode Films
在线阅读 下载PDF
导出
摘要 采用直流磁控溅射法制备了析氢反应的电极材料-N iFe,CoMo,研究了在1.0Pa^4.0Pa的范围内,不同溅射腔气压条件下制备的电极材料的晶粒尺寸、析氢反应的过电位与气压的关系,结果显示过电位随气压升高而降低,而且在2.0Pa处,过电位变化的程度和Tafel斜率均发生突变,表明不同溅射气压下制备的材料晶粒尺寸的变化,引起了析氢反应控制步骤的改变。 Using DC magnetron sputtering device to prepare hydrogen evolution reaction （HER） electrodes, at the rang of 1.0-4. 0Pa, catalysis electrode films of NiFe, CoMo of HER prepared at different sputtering pressure, their crystal size and HER overpotential decreased with increasing of chamber pressure, and their overpotential and Tafel slope were changed sharply at 2.0Pa. These showed that crystal size is crucial factor to the step of HER, and Tafel slope changed with it.
作者 宋红 张庆宝 魏长春 耿新华
机构地区 南开大学光电子薄膜器件与技术研究所 光电子薄膜器件与技术天津市重点实验室 光电信息技术科学教育部重点实验室(南开大学天津大学)
出处 《人工晶体学报》 EI CAS CSCD 北大核心 2006年第6期1291-1295,共5页 Journal of Synthetic Crystals
关键词 析氢电极材料 气压 过电位 晶粒尺寸 catalysis electrode films sputtering pressure overpotential crystal size
分类号 TN201 [电子电信—物理电子学]
  • 相关文献

参考文献11

  • 1Raney M.[P]. U.S. Patent:1563787 (1925), 1628191(1927).
  • 2Brown D E, Mahmood M N, Turner A K, Hall S M [J]. Int. J. Hydrogen Energy, 1982,7 : 405-408.
  • 3Birkenstock U, Holm R, Reinfandtand B, Storp S [J]. J. Catalysis, 1985,93:55.
  • 4Kleinand J C,Herculers M [J]. Anal. Chem., 1984,56685.
  • 5Vishnevetskii E A, Mikhallenkoand S D, et al [J]. React. Kinet. Catal. Lett., 1986,31:445.
  • 6Divisek J, Schmitz H [J]. J. Appl. Electrochem. 1989,19(4):519.
  • 7马杰 蒋雄 江琳才 等.球磨形成的Ni—Mo纳米晶复合镀层上的析氢反应[J].J. of Physical Chemisty,1996,12:22-28.
  • 8Arul Raj I, Venkatesan V K. Characterization of Nickel Molybdenum and Nickel Molybdenum Iron Ally Coating as Cathodes for Alkaline Water Electrolysis [J] Int. J. Hydrogen Energy, 1988, 13 (4): 215-223.
  • 9Hall D E, Shepard V R, Jr. AB5 Catalyzed Hydrogen Evolution Cathodes[J]. Int. J. Hydrogen Energy,1984, 9:1005-1009.
  • 10Hall D E, Sarver J M, Gothard D O. Hydrogen Evolution Cathodes with AB5 Catalyzed Coating [J] Int. J. Hydrogen Energy, 1988,13, 547- 561.

二级参考文献8

  • 1Bak T,Nowotny J,Rekas M,Sorrell C C.Photo-electrochemical Hydrogen Generation from Water Using Solar Energy Materials-related Aspects[J].Int. J. Hydrogen Energy,2002,27:991-1022.
  • 2查全性.电极过程动力学导论第二版[M].北京科学出版社,1987.487.
  • 3Miller E L,Rocheleau R E,Deng X M.Design Consideration for a Hybrid Amorphous Silicon/Photoelectrochemical Multijunction Cell for Hydrogen Production[J].Int. J.Hydrogen Energy,2003,28:615-623.
  • 4Kibria M F,Mridha M S.Electrochemical Studies of the Nickel Electrode for the Oxygen Evolution Reaction[J].Int. J. Hydrogen Energy,1996,21:179.
  • 5Corrigan D.The Catalysis of Oxygen Evolution Reaction by Iron Impurities in Thin Film Nickel Oxide Electrode[J].J. Electrochem. Soc.,1987,134:377.
  • 6Eric Miller L,Richard Rocheleau E.Electrochemical and Electrochromic Behavior of Reactively Sputtered Nickel Oxide[J].J. Electrochem. Soc.,1995,144(6):1997.
  • 7Eric Miller L,Richard Rocheleau E.Electrochemical and Electrochromic Behavior of Reactively Sputtered Iron-doped Nickel Oxide[J].J.Electrochem Soc.,1997,144(9):3072.
  • 8Satom H,Minami T,Takata S, Yamada T.Transparent Conducting P-type NiO Thin Films Prepared by Magnetron Sputtering[J].Thin Solid Films,1993,236:27.

共引文献6

人工晶体学报
2006年 第6期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部