摘要
无机层状化合物是一类具有规整层状结构的化合物,其层板上骨架阳离子的可替代性以及层间离子的可交换性引起了研究者的广泛兴趣。通过调变层板骨架阳离子、表面负载活性物种、层间柱撑无机或有机基团合成了各种新型功能性层状材料,并在酸碱催化、光催化、环保以及医药等领域有着广泛的应用。详细介绍了近年来新型层状化合物的合成及应用进展。
Inorganic layered materials are a class of compounds that possess regular lamellar structure. The unique properties of the layered materials, including the substitutability of the framework cations in the layer and the exchangeability of the interstitial ions have attracted a growing interest. Many functional layered materials have been prepared by altering the cations, intercalating inorganic/organic groups and loading the active species on the surface. These novel materials are widely used in basic-acid catalysis, photocatalysis, ion exchange, adsorption, environmental protection, medicine and so on. The latest development in the synthesis and applications of layered materials is reviewed.
出处
《材料导报》
EI
CAS
CSCD
北大核心
2006年第12期96-99,103,共5页
Materials Reports
基金
国家自然科学基金项目(NSFC:20273031
20373024)
关键词
层状材料
功能化
催化剂
柱撑
layered materials, functionalization, catalyst, pillar
