摘要
采用统计力学及过渡态理论对反应Ｈ２Ｎ＝Ｎ→Ｎ２＋Ｈ２的力学量进行计算，给出了气相分子Ｈ２Ｎ＝Ｎ的标准热力学函数，同时计算了该反应的平衡常数。采用经典过渡态理论计算了该反应的速度常数，并对计算结果进行了隧道效应的校正。
The dynamic value of the reaction of H2N=N→N2+H2, was computed by using statistical mechanies and transition -state theory. The standard thermodynamic function of gaseous molecule H,N￣N was given in this paper, and the equilibrium constant of H,N2=→H +N2 was also computed,and was corrected by tunneling effect.
出处
《河北师范大学学报（自然科学版）》
CAS
1996年第2期65-67,78,共4页
Journal of Hebei Normal University：Natural Science
关键词
分解反应
标准热力学
反应速度常数
力学量
H_2N=N
decomposition reaction
standard thermodynamic function
rete constant
