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改性羧甲基纤维素膜的制备及其在氨氮废水处理中的应用 被引量:4

Preparation of CMC-Fe Membrane and Study on Application in Electrodialysis for Treating Wastewater
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摘要 以F eC l3改性羧甲基纤维素(CM C),使得水溶性CM C膜改性为疏水性阳离子交换膜CM C-F e,该膜能稳定存在于酸碱溶液中.用扫描电镜观察其表面形态,IR分析表明改性羧甲基纤维素中的-COOH吸收峰发生了位移.将其应用于电渗析去除高浓度氨氮废水的处理中,结果表明,该膜对氨氮的选择透过性较好,能有效地去除水中氨氮,去除率可达90%.NH4+的迁移过程符合一级反应动力学. An insoluble CMC-Fe membrane was prepared by being linked soluble carboxymethylcellulose with FeCl3. The membrane as a cationic exchanging membrane in electrodialysis was applied in treating wastewater with high concentration of inorganic ammonia and azote. The results of experiment showed that it was well-selective to ammonia and azote. The percentage of the removal of ammonia and azote in wastewater is up to 90%. The migration process of NH4^+ is following one class reaction kinetics.
出处 《福建师范大学学报(自然科学版)》 CAS CSCD 北大核心 2006年第4期63-66,共4页 Journal of Fujian Normal University:Natural Science Edition
基金 福建省自然科学基金资助项目(A9910009) 福建省教育厅资助项目(JB05314JA02189)
关键词 改性羧甲基纤维素 离子交换膜 电渗析 氨氮 carboxymethyl-cellulose ion-exchange membrane electrodialysis ammonia and azote
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参考文献7

  • 1Grebenyuk V D, Grebenyuk O V. Electrodialysis: from an idea to realization [J]. Russion Journal of Electro-Chemistry, 2002, 38 (8): 806-809.
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