摘要
以NKC-9阳离子交换树脂为催化剂,在微波条件下用1-萘乙酸和甲醇合成1-萘乙酸甲酯。最佳合成条件为:醇酸摩尔比为14:1,催化剂为1-萘乙酸的80%,微波辐射时间为15分钟,微波功率为600瓦,产率为80.48%。
The methyl 1-naphthylacetate was synthesized by 1-naphthylene acetic acid and methanol with NKC-9 resin as catalyst under microwave irradiation. The optimum reaction conditions were as follows： the mole ratio of alcohol to carboxylic acid was 14：1, the catalyst was 80% of 1-naphthyl acetic acid, the reaction time was 15rain, the microwave power was 600 w, the yield was 80.48%.
基金
湖北省科技厅资助项目
项目号2004AA101C87.
关键词
1-萘乙酸
合成
微波辐射
阳离子交换树脂
1-萘乙酸甲酯
1-naphthylacetic acetic acid
synthesis
microwave irradiation
NKC-9 resin
methyl 1-naphthylacetate
