摘要
基于化学浴沉积法,采用硫酸锌、硫脲、水合肼和氨水混合溶液于适当温度下在玻璃衬底上沉积得到表面均匀的ZnS薄膜.对在不同沉积时间以及退火时间下得到的ZnS薄膜运用X射线衍射法观测其晶型结构,发现较长的沉积时间(5 h)和退火时间(3 h)制得的薄膜结晶度好,且检测出为闪锌矿晶型.并对其透光性能做了检测,发现pH值对透光度有显著影响.
ZnS thin films were prepared by chemical bath deposition （CBD） , using mixed aqueous solutions of zinc sulfate, thiourea, hydrazine hydrate and ammonia on glass sides, the as-deposited thin films were surface homogeneous. The crystal structure of ZnS thin films obtained under different deposition time and anneal time conditions is studied by XRD and it indicates that adequate deposition time（5 h）and anneal time（l h） is very good to grow highly crystalized ZnS thin films of sphalerite structure. Optical transparency property is also discussed and it is found that pH value has an obvious influence on it.
出处
《信阳师范学院学报（自然科学版）》
CAS
北大核心
2006年第4期483-485,共3页
Journal of Xinyang Normal University(Natural Science Edition)
关键词
ZNS薄膜
化学浴沉积法
XRD
ZnS thin films
chemical bath deposition （CBD）
XRD
