摘要
非水溶剂中八丁氧基2,3萘酞菁氯锰(Ⅲ)的电化学研究①杨素苓刘尔生陈耐生黄金陵(福州大学化学系,福州350002)王晓玉卜平段武彪吴谊群左霞(黑龙江大学化学系,哈尔滨150080)金属萘酞菁配合物由于含有比相应的酞菁配合物更大的π共轭体系,因而具...
The electrochemical behavior of 5,9,14,18,23,27,32,36 Octa Butyl 2,3 Naphalocyanine Manganese (Ⅲ) [(BuO) 8NPcMn(Ⅲ)Cl] in four nonaqueous solvents was studied by means of cyclic voltammetry, and the corresponding half wave potentials (E 1/2 ) of redox reactions were obtained. Four (or five) pairs of redox peaks were assigned. The solvent effect on the electrochemical characteristics of this coordination compound was also discussed preliminarily, and the electrochemical behavior of the complex was compared with that of nonsubstitued naphthalocyanine.
出处
《电化学》
CAS
CSCD
1996年第4期448-451,共4页
Journal of Electrochemistry
基金
黑龙江省自然科学基金
关键词
非水溶剂
八丁氧基
萘酞菁氯
锰配合物
Octa buty1 2
3 naphthalocyanine manganese (Ⅲ)
Electrochemistry
Nonaqeous solvents