摘要
报道了咪唑、吡啶、二甲氨基吡啶、三乙胺和噻吩嗪对尾式缬氨酸卟啉［５－对－（Ｎ－缬氨酸丁氧基）苯基－１０，１５，２０－三（对氯苯基）卟啉］钻（Ⅱ）、铁（Ⅲ）、锰（Ⅲ）配合物电子光谱的影响．实验结果表明，这些含Ｎ、Ｓ轴向配体对金属卟啉轴向加合能力由大至小的顺序为：噻吩嗪咪＞咪唑＞吡啶（≈二甲基吡啶）＞三乙胺．
The essay gives an account of the effect of some axial ligands such as imidazole,pyridine dimethylaminopyridine, trithylamine and thiodiphenylamine on the electronic spectrum of tailed valine metelloporphyrins complexes and concludes that their coordinated power diminish as follows: TDPA>Im>Py(≈DMAAp)>TEA.
出处
《淮北煤师院学报（自然科学版）》
1996年第4期52-55,共4页
Journal of Huaibei Teachers College(Natural Sciences Edition)
基金
湖北省教委科学基金
