期刊文献+

石油中有机钙化合物脱除反应的研究 被引量:5

STUDY ON REMOVING ORGANIC CALCIUM FROM CRUDE OIL
在线阅读 下载PDF
导出
摘要 以原油中的有机钙为研究对象,考察各条件对有机钙脱除反应的影响。结果表明:有机钙的脱除率随着脱钙剂加入量、注水率、反应温度、反应时间的增加而提高;脱钙反应在弱酸性溶液中进行较为有利,脱钙剂水溶液的pH值以6.5为佳;有机钙脱除过程是含有脱钙剂的水相从油相中萃取金属钙的化学萃取过程,受扩散和化学反应双重控制。 The impact of different reaction conditions on the removal rate of organic calcium from crude oil is investigated. The study demonstrates that organic calcium removal rate increases with increasing amount of decalcification agent addition, injected water, reactor temperature and reaction time. The weak sour solution is favorable for decalcification reaction and decalcification agent works best at a liquid solution pH value of 6.5. The decalcification process is a chemical extraction process for extracting organic calcium from oil phase by water phase containing decalcification agent. Furthermore, the extraction process is subject to diffusion, and chemical reaction control.
出处 《炼油技术与工程》 CAS 北大核心 2006年第8期38-41,共4页 Petroleum Refinery Engineering
关键词 原油 钙化合物 脱除率 注水率 脱钙剂 实验室规模 crude oil, calcium compound, removal rate, injected water, decalcification agent, laboratory scale
  • 相关文献

参考文献8

二级参考文献17

  • 1李勇志,吴文辉,陆婉珍.辽河原油中羧酸的分布及其结构组成[J].石油学报(石油加工),1989,5(4):62-69. 被引量:22
  • 2李恪,张景河,赵晓文,罗玉馥,徐成东.克拉玛依九区原油中石油羧酸组成和结构的研究[J].石油学报(石油加工),1995,11(2):100-108. 被引量:10
  • 3张佩甫.原油中金属杂质的危害及脱除方法[J].石油化工腐蚀与防护,1996,13(1):9-11. 被引量:22
  • 43,John G,Reynolds,El C.Demetalation of Hydrocarbonaceous Feedstocks Using Carbonic Acid and Salts Thereof.美国,US 4,778,591.1988
  • 54,John G,Reynolds,El C,David C,Kramer,San A.Demetalation of Hydrocarbonace ous Feedstocks Using Monobasic Carboxylic Acids and Salts Thereof.美国,US 4,988, 433.1991
  • 65,John G,Reynolds,El C.Demetalation of Hydrocarbonaceous Feedstocks Using Dibasic Carboxylic Acid and Salts Thereof.美国,US 4,853,109.1989
  • 78,David C.K.Demetalation of Hydrocarbonaceous Feedstocks Using Sulfuric Ac id and Salts Thereof.美国,US 5593573.1997
  • 811,Chi-Wen Hung,Reynolds,Bruce E.Catalyst System for Removal of Calcium f rom a Hydrocarbon Feedstock.美国,US 4,741,821.1988
  • 912,Chi-Wen Hung,Bruce E.Reynolds,Martinez.Catalyst System for Removal of Calcium from a Hydrocarbon Feedstock.美国,US 5,102,852.1992
  • 1013,Chi-Wen Hung,Bruce E.Reynolds,Martinez.Catalyst System for Removal of Calcium from a Hydrocarbon Feedstock.美国,US 5,143,887.1992

共引文献118

同被引文献14

引证文献5

二级引证文献9

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部