摘要
通过详细野外调查和室内鉴定分析，研究了支家庄铁矿的蚀变矿化特征，推测了热液性质及其演化。该矽卡岩型铁矿与黑云母花岗岩和高于庄白云岩有关。外矽卡岩带规模较大，内矽卡岩带规模较小。接触变质之后，蚀变矿化经过了透辉石－石榴石、金属氧化物、金属硫化物、碳酸盐四个阶段。磁铁矿主要在金属氧化物阶段大量沉淀于外矽卡岩带中，稍后有弱硼镁铁矿化。矽卡岩和矿化从岩体到围岩总体上有分带现象。热液主要为岩浆来源，随时间演化和远离岩体，天水混入程度增加。根据流体包裹体测温数据和化学成分推测了热液温度、压力、盐度、氧逸度。
The Zhijiazhuang skarn iron deposit is in Laiyuan County, Hebei Province and is now being mined in open pit. Biotite granite, porphyritic granite, alaskite and diorite porphry are discovered in the camp but only biotite granite is closely related to the mineralization. The altered wall rock is dolomite interbeded with chert stripes of the Mid Proterozoic Gaoyuzhuang Formation. Along with the emplacement of biotite granite, the dolomite was thermally metamorphized to dolomitic marble, forsterite marble and periclase marble. The intrusive rocks underwent albitization. Four stages of contact metasomatism are noted. In the first stage, biotite granite was altered to calcic skarn which consisted mainly of diopsidic pyroxene, andradite and trace schorlomite, seyrigite, while the marbles were replaced by diopside, forsterite and minor spinel which comprised the magnesian skarn. The Th of inclusions in andradite>540℃;diopside in calcic skarn 450～520℃;diopside in magnesian skarn 370～420℃;During retrograde alteration, the calcic akarn was replaced by epidote with minor tremolite, phlogopite, chlorite and serpentine. In magnesisan skarn, chondrodite replaced forsterite, fine grained diopside and minor tremolite replaced diopside, then they all were replaced by phlogopite, chlorite and serpentine. Magnetite began to deposit after the formation of phlogopite and before serpentinization mainly in exoskarn, followed by the deposition of ludwigite which was replaced later by szaibelyite. The decrepitation temperature of magnetite is 345℃; Afterwards, minor serpentine, calcite, chlorite and pyrrhotite, pyrite, chalcopyrite, galena, sphalerite were precipitated in the sulfide stage. Most of the sulfides are found in magnesian skarn adjacent to endoskarn. The Th of fluid inclusions in calcite of this stage is 250～300℃. In the final carbonate stage, minor calcite and aragonite filled in fissures, apophyllite grew in vugs or replaced early minerals, brucite replaced periclase. The size of exoskarn is much larger than that of endoskarn. Roughly the skarns are zoned with respect to diopside/andradite ratio in calcic skarn, diopside/serpentine ratio in magnesian skarn, the intensity of retrograde alteration and ore petrography. According to chemical composition of inclusions in diopside, the physiochemical conditions of the fluids are infered: salinity:51.01%NaCl eq proximal, 47.87%NaCl eq distal; pressure: 23 MPa,f O 2 about 10 -23 Pa, pH: 7.58.
出处
《北京大学学报（自然科学版）》
CAS
CSCD
北大核心
1996年第6期724-733,共10页
Acta Scientiarum Naturalium Universitatis Pekinensis
基金
高等学校博士学科点专项科研基金
关键词
矽卡岩铁矿
液包体
蚀变矿化
铁矿
矿化
Zhijiazhuang
skarn iron deposit
alteration and mineralization
fluid inclusion
