摘要
Two new complexes CdL2 (1) and CoL2 (2) were synthesized by reactions of L {L =hydrobis(3-p-tolyl-2-thioimidazol-1-yl)-(3-phenyl-5-methyl-pyrazol-1-yl)borate} with cadmium(II) and cobalt(II) acetate respectively, and structurally characterized. The title complexes feature distorted trigonal dipyramidal geometries with a S4H donor set defined by the sulphur and hydrogen atoms of two tripodal sulfur-rich ligands. CCDC: 235514, 1; 244021, 2.
Two new complexes CdL2 （1） and CoL2 （2） were synthesized by reactions of L {L =hydro[bis（3-p-tolyl-2- thioimidazol-1-yl）-（3-phenyl-5-methyl-pyrazol-1-yl）]borate} with cadmium（Ⅱ） and cobah（Ⅱ） acetate respectivelyl, and structurally characterized. The title complexes feature distorted trigonal dipyramidal geometries with a S4H donor set defined by the sulphur and hydrogen atoms of two tripodal sulfur-rich ligands. CCDC： 235514, 1; 244021, 2.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第8期1507-1510,共4页
Chinese Journal of Inorganic Chemistry
基金
教育部留学回国人员科研启动基金资助项目
关键词
三角架配体
镉
钴
晶体结构
tripodal ligand
cadmium
cobalt
crystal structure
