摘要
通过对乙酸和乙醇酯化反应体系的相平衡计算，分析了乙酸对乙醇－乙酸乙酯－水共沸组成的影响，确定了消除三元共沸物的最小乙酸浓度。试验考查了萃取反应精馏流程用于合成乙酸乙酯的可操作性，探讨了各操作参数对产品酯纯度的影响规律。结果表明，单塔流程得到的酯纯度可达９７％以上，产品中的杂质主要是水，乙醇的含量小于０．３％。
The effects of acetic acid on alcohol acetate water azeotropic composition were analyzed by calculations of phase aquilibrium of the esterification system The minimum amount of acid for eliminating ternary azeotrope was determined The feasibility of extractive reactive distillation for the preparation of pure ethyl acetate and the effects of reaction conditions on the composition of distillate were also investigated in the laboratory
出处
《石油化工》
CAS
CSCD
北大核心
1996年第10期719-723,共5页
Petrochemical Technology
关键词
萃取反应精馏
酯化
乙酸乙酯
extractive reactive distillation,esterification,ethyl acetate
