期刊文献+

合成气合成乙二醇工艺进展和展望 被引量:45

Recent Progresses in the Study on the Conversion of Syngas to Ethylene Glycol
在线阅读 下载PDF
导出
摘要 介绍了合成气合成乙二醇的工艺进展情况,包括合成气直接合成法、甲醇甲醛合成法和草酸酯法等。在比较不同工艺路线的同时,从现有的经济技术条件出发,尤其是根据原油价格高涨的实际情况和预期,提出了大力发展甲醇甲醛合成法和草酸酯法合成乙二醇的战略思路。 Recent progresses in the study on the conversion of syngas to ethylene glycol, including direct synthesis by syngas and indirect synthesis by methanol and formaldehyde or oxalate, are introduced. Based on the fact and anticipation of high crude oil price, and comparison of various synthesizing routes, it is suggested that the routes using methanol and formaldehyde or oxalate as the intermediums should be developed according to the recent economical and technological conditions.
出处 《天然气化工—C1化学与化工》 CAS CSCD 北大核心 2006年第3期56-60,共5页 Natural Gas Chemical Industry
关键词 合成气 乙二醇 甲醇 甲醛 草酸酯 syngas ethylene glycol methanol formaldehyde oxalate
  • 相关文献

参考文献19

  • 1W F Gresham.Preparation of polyfuctional compounds[P].US:2 636 046,1948.
  • 2高占笙.合成气一步制乙二醇[J].石油化工,1993,22(2):137-141. 被引量:19
  • 3Baanaado D D,Pooru U H,Jiyooji R O.Process for producing alcohols[P].JP:5 8131 926,1984-10-23.
  • 4Knifton,John F.Process for low pressure synthesis of ethylene glycol from synthesis gas plus formaldehyde[P].US:4 616 097,1982-10-22.
  • 5Stephen H Brown,Robert H,Crabtree.Alkane functionalization on a preparative scale by mercury-photosensitized cross-dehydrodimerization[J].Am Chem Soc,1989,111(8):2946-2953.
  • 6钟顺和,高峰,叶文强,肖秀芬.激光促进磷酸盐表面甲醇氧化偶联反应[J].应用化学,2000,17(3):238-242. 被引量:15
  • 7孟宪申.21世纪以煤和天然气为原料的C_1化学[J].化工技术经济,2000,18(2):1-5. 被引量:19
  • 8Yagita H,Asami K,Muramatsu A,et al.Oxidative dimerization of dimethyl ether with solid catalysts[J].Appl Catal,1989,53(1):L5-L9.
  • 9张军.天然气路线合成乙二醇新技术[J].合成技术及应用,2004,19(2):22-25. 被引量:12
  • 10Scardigno,Salvatore,Rivolta,et al.Process for preparing glycolic acid and its polymers[P].US:4 052 452,1977.

二级参考文献27

  • 1钟顺和,马红钦.激光促进甲烷氧化偶联表面反应规律的研究[J].分子催化,1994,8(2):91-98. 被引量:16
  • 2陈庚申 陈贻盾(Chen G Sh Chen Y D).[P].CN 85/101616.1986.
  • 3[1]Kenji N, Kozo F, Keigo N, et al. Process for Preparing a Diester of Oxalic Acid in the Gaseous Phase. USA, US 4 229 591. 1980
  • 4[2]William J B, Charleston W V. Ethylene Glycol by Catalytic Hydrogenation. USA, US 4 628 128. 1986
  • 5[10]Ried R C, Prausnitz J M, Sherwood J K. The Properties of gas and liquid. 4 th ed. New York: McGraw-Hill Book Company,1987
  • 6[2]Jiang X Z, Su Y H, Lee B J, et al. A Study on the Synthesis of Diethyl Oxalate over Pd/α-Al2O3 Catalysts. Applied Catalysis A:Ceneral, 2001,211 : 47 ~ 51
  • 7[3]Xu G H, Ma X B, He F, et al. Characteristics of Carbon Monoxide Coupling Reaction. Industry Engineering Chemical Research,1995,34 (7) : 2379~ 2382
  • 8张俊忠,天然气化工,1987年,6期,26页
  • 9辛秀兰,博士学位论文,1997年
  • 10郭光生,石油化工,1993年,22卷,3期,204页

共引文献130

同被引文献371

引证文献45

二级引证文献290

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部