摘要
选用N-乙烯基吡咯烷酮和间苯型不饱和聚酯为单体,合成了新型两亲性的超高交联吸附树脂(NU)。通过静态吸附实验,研究了NU树脂在不同温度下吸附水溶液中p-硝基苯酚的热力学和动力学特性,结果表明,吸附符合一级动力学方程,NU树脂吸附p-硝基苯酚符合Freundlich模型,通过计算△H<0,为放热反应。
New amphiphilic hypercrosslinked polymeric resins （NU） of isophthalie unsaturated polyester which was copolymerized with N-vinylpyrrolidone for removing p-nitrophenol from their aqueous solutions were prepared. The adsorption kinetics and thermodynamics of p-nitrophenol was carried out through static experiments. The results showed that the process of dynamics for the adsorption can be simulated by first order kinetic model. The adsorption date of p-nitrophenol onto the NU resin fit well into the Freundlich isotherm. AH was obtained and it is lower than zero, which indicated that the adsorption was exothermic reaction.
出处
《化工新型材料》
CAS
CSCD
北大核心
2006年第5期38-41,共4页
New Chemical Materials
