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一种由[Ag(CN)_2]^-和Mn(Ⅱ)建筑块组装的三个三维网穿插的超分子配合物的结构和荧光性质(英文)

Three Interpenetrating 3D Related Networks and Luminescence of a Supramolecular Assembly Containing [Ag(CN)_2]^-and Mn(Ⅱ) Tectons
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摘要 Three interpenetrating 3D related networks of a cyano-bridged heterometallic supramolecular complex {KMn Ag(CN)2 3·H2O}n (1) have been synthesized, and characterized by single crystal X-ray diffraction. The solid state of 1 displays interesting luminescence determined by argentophilicity at room temperature. CCDC: 197205. Three interpenetrating 3D related networks of a cyano-bridged heterometallic supramolecular complex {KMn[Ag(CN)2]3·H2O}n (1) have been synthesized, and characterized by single crystal X-ray diffraction. The solid state of 1 displays interesting luminescence determined by argentophilicity at room temperature. CCDC: 197205.
作者 张建华 董文
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2006年第6期1159-1162,共4页 Chinese Journal of Inorganic Chemistry
基金 国家自然科学基金项目(No.20471031,20331010)。
关键词 超分子配合物 亲银作用 荧光性 supramolecular complex argentophilicity luminescence
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