摘要
The synthesis of nickel supramolecular compound with hexamethylenetetramine and fumarate ligands is reported. The compound Ni(H2O)6(fum) ·2(hmt)·4H2O (1) (fum=fumarate; hmt=hexamethylenetetramine) were characterized by elemental analysis, crystal structure, IR. Compound 1 crystallizes in the triclinic system, space group P1, and with Z=1. Cell parameters: a=0. 934 6(1), b=0.933 8(1), c=0.938 8(2) nm, α=79.46(1)°, β=77.84(1)°, γ=61.29 6(7)°. Every metal ion has a octahedral coordination geometry formed by six oxygen atoms from six water molecules, and the relative independent components Ni(H2O)6 2+, fumarate anions, hmt and H2O molecules are linked together by two kinds of hydrogen bonds (O-H...O, and O-H...N) to form a three-dimensional structure. CCDC: 256355.
The synthesis of nickel supramolecular compound with hexamethylenetetramine and fumarate ligands is reported. The compound [Ni （H2O）6（fum）]·2 （hmt） ·4H2O （1） （fum =fumarate; hint =hexamethylenetetramine） were characterized by elemental analysis, crystal structure, IR. Compound 1 crystallizes in the triclinic system, space group P1^-, and with Z=1. Cell parameters： a=0. 934 6（1）, b=0.933 8（1）, c=0.938 8（2） nm, α=79.46（1）°, β=77.84（1）°, γ=61.29 6（7）°. Every metal ion has a octahedral coordination geometry formed by six oxygen atoms from six water molecules, and the relative independent components [Ni（H2O）6]^2＋, fumarate anions, hmt and H2O molecules are linked together by two kinds of hydrogen bonds （O-H…O, and O-H…N） to form a three-dimensional structure. CCDC： 256355.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第6期1095-1098,共4页
Chinese Journal of Inorganic Chemistry
基金
江苏省教育厅自然科学基金(No.05KJB15002)
江苏工业学院自然科学基金资助项目。
