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The Mechanism on Cyclization, Debenzylation and Oxidation of 1-[1-(Benzyloxy)-3-methylnaphthalen-4-yloxy]propan-2-one 被引量:1

The Mechanism on Cyclization, Debenzylation and Oxidation of 1-[1-(Benzyloxy)-3-methylnaphthalen-4-yloxy]propan-2-one
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摘要 1-[1-(Benzyloxy)-3-methylnaphthalen-4-yloxy]propan-2-one (la) took place a cyclization, debenzylation and oxidation to form 9-substitued benzo[de]chromene-7,8-dione (2a) and 5-benzyl-9-substitued benzo[de]chromene-7,8-dione (3a). The mechanisms for these reactions were discussed. 1-[1-(Benzyloxy)-3-methylnaphthalen-4-yloxy]propan-2-one (la) took place a cyclization, debenzylation and oxidation to form 9-substitued benzo[de]chromene-7,8-dione (2a) and 5-benzyl-9-substitued benzo[de]chromene-7,8-dione (3a). The mechanisms for these reactions were discussed.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2006年第6期769-772,共4页 中国化学快报(英文版)
基金 We are indebted to the National Natural Science Foundation of China (No.20272085,20472117) the Guangzhou City Science Foundation,the Guangdong Provincial Science Foundation(031594) the Scientific Research Foundation for the Returned 0verseas Chinese Scholars,and the HongKong Polytechnic University Area of Strategic Development Fund for financial support of this study.
关键词 Mansonone F CYCLIZATION selenium dioxide [2 3]sigmatropic rearrangement. Mansonone F, cyclization, selenium dioxide, [2,3]sigmatropic rearrangement.
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