Asymmetric Syntheses of Osmundalactones and 5-Hydroxy-2-hexen-4-olides from 4-Benzyloxy-5-hydroxy-2(E)-hexenoate

Asymmetric Syntheses of Osmundalactones and 5-Hydroxy-2-hexen-4-olides from 4-Benzyloxy-5-hydroxy-2(E)-hexenoate

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摘要（＋）-（4S,5R）-and （-）-（4R,5S）-osmundalactones as well as （＋）-（4R,5S）- and （-）-（4S,5R）- 5-hydroxy-2-hexen-4-olides were synthesized by a concise and efficient synthesis method starting from 4-benzyloxy-5-hydroxy-2（E）-hexenoate in good yield with over 99% e.e.. （＋）-（4S,5R）-and （-）-（4R,5S）-osmundalactones as well as （＋）-（4R,5S）- and （-）-（4S,5R）- 5-hydroxy-2-hexen-4-olides were synthesized by a concise and efficient synthesis method starting from 4-benzyloxy-5-hydroxy-2（E）-hexenoate in good yield with over 99% e.e..

作者 Xi Ying ZHAO Machiko ONO Hiroyuki AKITA Yu Ming CHI

机构地区 Beijing University of Traditional Chinese Medicine and Pharmacy School of Pharmaceutical Sciences Seiwa Pharmaceutical. Ltd.

出处《Chinese Chemical Letters》 SCIE CAS CSCD 2006年第6期727-729,共3页 中国化学快报（英文版）

关键词 Osmundalactone 5-hydroxy-2-hexen-4-olide 4-benzyloxy-5-hydroxy-2（E）-hexenoate. Osmundalactone, 5-hydroxy-2-hexen-4-olide, 4-benzyloxy-5-hydroxy-2（E）-hexenoate.

分类号 O623.4 [理学—有机化学]

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Chinese Chemical Letters

2006年第6期

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Asymmetric Syntheses of Osmundalactones and 5-Hydroxy-2-hexen-4-olides from 4-Benzyloxy-5-hydroxy-2(E)-hexenoate

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