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Thermodynamics of Ion Pair of Magnesium Sulfate in Mixed Solvent

Thermodynamics of Ion Pair of Magnesium Sulfate in Mixed Solvent
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摘要 Introduction Magnesium sulfate is an archetypal 2-2 salt that plays a central role in defining the characteristics of higher valent electrolyte solutions and its solution has been widely used to test various theories of strong electrolyte behavior and to develop models of ion association in solution. Up to now, the ion pairs of magnesium sulfate in an aqueous solution have been widely investigated by using different experimental techniques, such as conductometry , cryoscopy potentiometry solubility and Raman spectrometry. However, to our knowledge, no measurement of the standard association constant of the ion pairs, [ MgSO4 ]^0 in a glucosewater mixed solvent is available. Introduction Magnesium sulfate is an archetypal 2-2 salt that plays a central role in defining the characteristics of higher valent electrolyte solutions and its solution has been widely used to test various theories of strong electrolyte behavior and to develop models of ion association in solution. Up to now, the ion pairs of magnesium sulfate in an aqueous solution have been widely investigated by using different experimental techniques, such as conductometry , cryoscopy potentiometry solubility and Raman spectrometry. However, to our knowledge, no measurement of the standard association constant of the ion pairs, [ MgSO4 ]^0 in a glucosewater mixed solvent is available.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2006年第3期403-405,共3页 高等学校化学研究(英文版)
基金 SupportedbytheNationalNaturalScienceFoundationofChina(No.20473036).
关键词 Association constant Mixed solvent MgSO4 Ion pair Association constant Mixed solvent MgSO4 Ion pair
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