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Magnetic Properties and Phase Transformation of Tb_(1-x)Pr_xFe_(1.96)(x=0 to 0.7) Compounds

Magnetic Properties and Phase Transformation of Tb_(1-x)Pr_xFe_(1.96)(x=0 to 0.7) Compounds
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摘要 The magnetic properties and the phase Transformation of Tb1-xPrx Fe1.96(x = 0 to 0.7) compounds were studied by means of vibrating sample magnetometer(VSM), X-ray diffraction(XRD) and SEM back-scattered electron (BSE). The result indicates that the saturation magnetization σs of compounds along an easy axis decreases with the addition of Pr contents, which reduces from 77.24 Am^2·kg^-1(x =0) to 11.84 Am^2·kg^-1(x =0.5) and then returns to 37.14 Am2·kg^-1 ( x = 0.7). The non-cubic phases appear when x exceeds 0.2, and the matrix of Tb1-xPrxFe1.96 compounds changes from (Tb, Pr)Fe2 phase with x = 0 to (Tb, Pr)Fe3 phase with x = 0.4, and at last to (Tb, Pr)2Fe17 phase in Tb0.3Pr0.7Fe1.96. Moreover, the structure, of the compounds may become more complex with the increase of Pr content. The magnetic properties and the phase Transformation of Tb1-xPrx Fe1.96(x = 0 to 0.7) compounds were studied by means of vibrating sample magnetometer(VSM), X-ray diffraction(XRD) and SEM back-scattered electron (BSE). The result indicates that the saturation magnetization σs of compounds along an easy axis decreases with the addition of Pr contents, which reduces from 77.24 Am^2·kg^-1(x =0) to 11.84 Am^2·kg^-1(x =0.5) and then returns to 37.14 Am2·kg^-1 ( x = 0.7). The non-cubic phases appear when x exceeds 0.2, and the matrix of Tb1-xPrxFe1.96 compounds changes from (Tb, Pr)Fe2 phase with x = 0 to (Tb, Pr)Fe3 phase with x = 0.4, and at last to (Tb, Pr)2Fe17 phase in Tb0.3Pr0.7Fe1.96. Moreover, the structure, of the compounds may become more complex with the increase of Pr content.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2006年第2期202-205,共4页 稀土学报(英文版)
基金 ProjectsupportedbyHighTechnologyDevelopmentProject(2002AA305305)
关键词 giant magnetostrictive materials TbPrFe compounds MAGNETIZATION phase transformation rare earths giant magnetostrictive materials TbPrFe compounds magnetization phase transformation rare earths
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