摘要
本文用高分辨~1H.NMR谱研究了多种短链芳烃及其衍生物在阳离子表面活性剂—十六烷基三甲基溴化铵(CTAB)水溶液胶束和非离子表面活性剂—月桂基聚氧乙烯(4)醚(Brij30)非水溶液胶束中的增溶作用。得到这些不同种类的增溶物在两种不同类型的胶束中增溶位置的详细结果。并讨论了增溶物与表面活性剂分子之间的相互作用。这一研究对深入探讨增溶机理十分有益。
In the aqueous micellar solution of hexadecyltrimethyl-ammonium bromide (CTAB) and non-aqueous micellar solution of polyoxyethylene 4-lauryl ether ( Brij 30), the solubilization of many kinds of short chain aromtic hydrocarbons and their derivatives were studied by high resolution proton nuclear magnetic resonance spectroscopy (1H-NMR) . The detailed results of the solubilization position of different kinds of solubilizates in two kinds of micelle had been obtained. The study will be very profitable to go further into the mechanism of the solubilization.
出处
《波谱学杂志》
CAS
CSCD
1990年第3期297-304,共8页
Chinese Journal of Magnetic Resonance
基金
国家自然科学基金资助课题
