摘要
通过固相缩聚合成了两种不同结构的高分子量共聚酯,研究了样品的熔融行为和结晶速率。研究发现,共聚酯的熔融峰随着固相聚合温度和时间的变化而与纯PET有明显的差别;共聚酯的结晶速率也慢于纯PET的结晶速率。
The melt behaviour and crystallization rate of two kind copolyesters(additive monomer:IPA and AA)prepared by solid state polycondensation were studied. The experimental results show that the changes of melt peaks of copolyesters with changing of S. S. P.temperature and time are different from PET homopolymer. In comparision with PET,the crystallization rate of both copolyesters are also decreased.
出处
《高分子材料科学与工程》
EI
CAS
CSCD
北大核心
1996年第3期127-130,共4页
Polymer Materials Science & Engineering
关键词
固相缩聚
熔融峰
结晶速率
共聚酯
聚合
s: copolyester, solid state polycondensation,melt peak, crystallization rate