摘要
用交联ＳＥ－５４ＳＣＯＴ玻璃毛细管柱分离了１－己烯羰化制庚醛过程的原料、产品及杂质，并采用气相色谱－质谱（ＧＣ－ＭＳ）技术和纯样对照法鉴定组分。与填充柱定量结果对比表明，毛细管气相色谱法简便、准确，具有实用价值。
The low-pressure carbonylation of 1-olefin is one of the main routes for the production of aldehydes. This paper presents a gas chromatographic method for the analysis of the raw material of 1-hexene, the product of heptaldehyde isomers and its by-products in this carbonylation process. A cross-linked SE-54 SCOT glass capillary column, 40m×0. 25mm (i. d.), was selected to analyse the raw material and the product in this process. GC-MS technique and comparison with pure samples were applied to the identification of the components. Meanwhile, the Kovats index of 1-hexene and 17 impurities in the raw material were calculated. Accuracy and precision of this method are acceptable.
出处
《色谱》
CAS
CSCD
北大核心
1996年第4期291-293,共3页
Chinese Journal of Chromatography
关键词
气相色谱
质谱法
庚醛
已烯
羰化
capillary gas chromatography, gas chromatography/mass spectrography, heptaldehyde, 1-hexene carbonylation
