摘要
本文报道了三苯基氧化膦与氯金酸形成的配合物 HAu Cl4.H2 O.4(C6H5) 3 PO的非等温热分解动力学 ,采用微分与积分相结合的方法 ,推断出了它的热分解反应机理 ,其热分解动力学方程为 :dα/dt=AΦe-E/ RT(32 ) (1 +α) ( 2 / 3 ) [(1 +α) ( 1 / 3 ) - 1 ]
In this paper,the thermoanalysis of title complex was studied. Kinetic parameters were obtained from analysisof TG,DTG curvesby integral and differential methods.The possible reaction mechanism was suggested by comparison of the kinetic parameters.The kinetic equation may be expressed as: dα dt=A Φe-E /R T(3/2 ) (1+α) ( 2 /3 ) [(1+α) ( 1 /3 ) - 1]-1
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1996年第2期215-217,共3页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目
