摘要
用停流分光光度法研究了氯代四苯基卟啉铁 ( ) [Fe T(p- X) PPCl,X=H,CH3 ]与肼在二氯甲烷溶液中的反应动力学 ,求得了不同温度下反应的速率常数及活化参数 ,初步探讨了反应机理。
The kinetics of reaction between chloroiron tetraphenylprophyrin Fe T(p- X) PPCl(X= H,CH3 ) and hydrazine hydrate in dichloromethane solution was investigated.The rate constant of the reaction at various temperature and active parameters were obtained. The mechanism of the reaction was explored.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1996年第2期126-129,共4页
Chinese Journal of Inorganic Chemistry
基金
天津市 2 1世纪青年基金资助课题
关键词
铁卟啉
肼
动力学
停流分光光度法
iron porphyrin hydrazine kinetics stopped- flow method
