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EO/PO无规共聚醚的浊点研究 被引量:10

Study on the Cloud Point of Ethylene Oxide/Propylene Oxide Random Copolymer
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摘要 研究了无规共聚醚水溶液的浓度、无规共聚醚结构及无机电解质、酸、醇、表面活性剂对浊点的影响。结果表明所选择的电解质均能降低聚醚的浊点;酸能轻微提高聚醚的浊点;水溶性醇和非水溶性醇的影响效果不同,前者能提高聚醚的浊点,后者则使之降低;表面活性剂能提高聚醚的浊点;随着聚醚中聚氧乙烯基含量的增加,其浊点升高;相对分子质量增加,使浊点降低。这些规律对无规聚醚的研究和应用有一定的指导意义。 The effects of concentration of aqueous solutions, structure of random copolyether, inorganic electrolytes, acids, alcohols, surfactants on the cloud point(CP) were studied. The results indicated that the CP of the random copolyether was decreased by electrolytes and increased slightly by acids. The effects of water soluble alcohols were different that of water insoluble alcohols. The CP was increased by the former, while decreased by the latter. The CP was increased by surfactants. With the rise of ethylene oxide in copolyether, the CP was raised. The CP was decreased with the enhancement of relative molecular weight. These laws will give some help for studying and applying of random copolyether.
出处 《东华大学学报(自然科学版)》 CAS CSCD 北大核心 2006年第2期30-34,共5页 Journal of Donghua University(Natural Science)
关键词 环氧乙烷 环氧丙烷 聚醚 浊点 ethylene oxide, propylene oxide, random copolyether, cloud point
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  • 1张晓光,张高勇,董金凤,王红霞.添加剂对非离子表面活性剂浊点的影响[J].日用化学工业,2002,32(4):7-10. 被引量:10
  • 2Abdulah M.Effect of olifield chemicals on the cloud point of nonionic surfactants.Colloid Surf A,1997,125:5-18
  • 3Gu T,Galera-Gómez P A.The effect of different alcohols and other polar organic additives on the cloud point of Triton X-100 in water.Colloid Surf A,1999,147:365 -370
  • 4Rodrigo Carsoso da Sila,Watson Loh.Effect of additives on the cloud points of aqueous solutions of ethylene oxidepropylene oxide-ethylene oxide block copolymers.J Colloid Interface Sci,1998,202:385-390
  • 5Goel S K.Predicting surfactant cloud point from molecular structure.J Colloid Interface Sci,1997,193:132-36
  • 6刘燕军,白云东,林非凡.化纤油剂用聚醚单体引发剂的选择[J].合成纤维工业,2000,23(6):46-48. 被引量:5
  • 7N J Jain.Salt induced micellization and micelle structures of PEO:PPO:PEO block copolymers in aqueous solution.Colloid Surf A,2000,173:85-94
  • 8Qiao L,Easteal A.Interaction between triton Ⅹ series surfactants and poly(ethylene glycol) in aqueous solutions.J Colloid Polym Sci,1998,276:313-320
  • 9Schott,H.Effect of inorganic additives on solutions of nonionic surfactants:Ⅹ.micellar properties.J Colloid Interface Sci,1995,173:265-277
  • 10Schott,H.Effect of inorganic additives on solutions of nonionic surfactants ⅩⅣ.effect of chaotropic anions on the cloud point of octoxynol 9 (Triton Ⅹ-100).J Colloid Interface Sci,1997,189:12-117

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