摘要
本文用MonteCarlo方法研究了逆反应对线性缩聚反应产物分子量分布和反应动力学的影响.模拟结果说明有逆反应的线性缩聚反应产物的分子量分布仍服从Flory分布;逆反应对反应动力学有较大影响.
The effect of reverse reaction on the molecular weight distribution (MWD) and kinetics of polycondensation reactions has been analysed by the Monte Carlo simulation method. The simulated MWD is in good agreement with the most probable MWD proposed by Flory. Reverse reactions affect kinetics of polycondensation reactions.
出处
《青岛大学学报(自然科学版)》
CAS
1996年第3期64-68,共5页
Journal of Qingdao University(Natural Science Edition)
关键词
缩聚反应
反应动力学
逆反应
蒙特卡罗模拟
polycondensation
Monte Carlo simulation method
kinetics of reaction