摘要
在溶液中用N-(邻苯甲酸基)-亚氨基二乙酸、苯并咪唑和Co(Ac)2·4H2O进行自组装合成了标题三元金属混配配合物。用元素分析、红外光谱、单晶衍射对配合物的组成和结构进行了表征,确定配体N-(邻苯甲酸基)-亚氨基二乙酸中的3个羧基为单齿形式与中心金属钴离子配位。
A new complex was synthesized by self-assembly in the solution with N-(o- carboxyphenyl) iminodiacetic acid, benzimidazole and Co (Ac) 2 · 4H2O, and characterized by elemental analysis,IR spectra and X-ray single crystal diffraction. The three carboxylic group of the N-(o- carboxyphenyl) iminodiacetic acid coordinate with the center Co ion as monodentate.
出处
《光谱实验室》
CAS
CSCD
2006年第2期194-197,共4页
Chinese Journal of Spectroscopy Laboratory
基金
广东省自然科学基金团队资助项目(No.04205301)