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混配配合物[Co(cpida)(C_7H_5N_2)_2]·C_7H_5N_2·5H_2O

Synthesis,Characterization and Structure of Mix-Ligand Complex[Co(cpida)(C_7H_5N_2)_2]·C_7H_5N_2·5H_2O
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摘要 在溶液中用N-(邻苯甲酸基)-亚氨基二乙酸、苯并咪唑和Co(Ac)2·4H2O进行自组装合成了标题三元金属混配配合物。用元素分析、红外光谱、单晶衍射对配合物的组成和结构进行了表征,确定配体N-(邻苯甲酸基)-亚氨基二乙酸中的3个羧基为单齿形式与中心金属钴离子配位。 A new complex was synthesized by self-assembly in the solution with N-(o- carboxyphenyl) iminodiacetic acid, benzimidazole and Co (Ac) 2 · 4H2O, and characterized by elemental analysis,IR spectra and X-ray single crystal diffraction. The three carboxylic group of the N-(o- carboxyphenyl) iminodiacetic acid coordinate with the center Co ion as monodentate.
出处 《光谱实验室》 CAS CSCD 2006年第2期194-197,共4页 Chinese Journal of Spectroscopy Laboratory
基金 广东省自然科学基金团队资助项目(No.04205301)
关键词 N-(邻苯甲酸基)-亚氨基二乙酸 苯并咪唑 混配配合物. N- (o-Carboxyphenyl) Iminodiacetic Acid,Benzimidazole,Mix-Ligand Complex.
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